Asymmetric Epoxidation of Dihydronaphthalene with a Synthesized Jacobsen’s Catalyst (2171 words, 12 pages)
Asymmetric Epoxidation of Dihydronaphthalene with a Synthesized Jacobsen'sCatalystJustin Lindsey120896Chem 250 GGProfessorTim HoytTA Andrea EgansAbstract. 1,2 diaminocyclohexane was reacted with L-()-tartaric acid to yield(R,R)-1,2-diaminocyclohexane mono-()-tartrate salt. The tartrate salt was thenreacted with potassium carbonate and 3,5-di-tert-butylsalicylaldehyde to yield(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine, which wasthen reacted with Mn(OAc)24H2O and LiCl to form Jacobsen's catalyst. Thesynthesized Jacobsen's ...
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